I'll split hairs and go w/ Windows Server 2003. It has all the XP kernel improvements, very little bloat, but sticks with a mostly Windows 2000 visual style. I ran it as a daily driver on a Thinkpad back in the 2004 - 2010 timeframe and really enjoyed it.
If you haven't heard about it already I think you'd be interested in the [ReactOS](https://en.wikipedia.org/wiki/ReactOS#Development) project which has been working on building an OS that is binary compatible with Windows Server 2003 while being GPL licensed. It's far from daily drivable but it's a fascinating little project.
YES, Windows Server 2003R2 was the best version of Windows ever. I worked with it professionally for about 8 years, if you just used MS software on it (exchange sql server etc) that thing NEVER crashed, when we deployed a 2003R2 (as opposed to a 2008/2008R2) we referred to it as deploying the VMS (openVMS).
BTW: However, i never used the 2003 64-bit version.