I bought the bundle a few months ago. The steam start process made the game wonky, so instead of going through the steam client, I made this batch file (for the 4th game):
@echo off
cd C:\Program Files (x86)\Steam\SteamApps\common\Commander Keen\base4
dosbox keen4e.exe -conf keen4.conf -exit
exit
The configuration file in question was modified, and these are the changes from the default that you might find useful, in the following sections:
Actually, I think I'm going to go buy it now... it's been too long since I've played Keen.