You're missing something vital here. They're not rejecting good candidates because they're good candidates, they're rejecting them because they're not sure enough that they're good candidates.
They fear they might be bad candidates. They'd rather reject too many than too few, so they make sure they reject everybody who they're not 100% is a good candidate. That means they may reject some good candidates that aren't easily identified as such, but it doesn't increase their chance of hiring a bad candidate; it decreases it.
They fear they might be bad candidates. They'd rather reject too many than too few, so they make sure they reject everybody who they're not 100% is a good candidate. That means they may reject some good candidates that aren't easily identified as such, but it doesn't increase their chance of hiring a bad candidate; it decreases it.