Well, nation states have only existed for 500 years or so, and marriage is mentioned in the Bible and plenty of Ancient Greek writings. I'm not sure if that counts as evidence here in reality-land.
With so narrow a definition of "nation state", I am left wondering what relevance "religious marriage existed long before nation states" has to the broader discussion.
States have existed far longer. "Nation state" refers specifically to a state which coincides with a cultural or ethnic group. If you had to choose a starting point for the idea of the nation state, the Treaty of Westphalia is one of the more reasonable.
Again, it depends on your definition of "state." If you're using the term interchangeably with the much broader term "government," which can include even the smallest and most primitive family or tribe power structures, then you can probably consider the state to be older than marriage (I actually think there's still room for debate even then, depending also on the definition of "marriage").
